Silylzincation of carbon-carbon multiple bonds revisited.


The first investigation of the copper-catalyzed silylzincation of alkynes as well as a diene and styrene using bis(triorganosilyl) zinc reagents led to the development of an efficient procedure and the disclosure of an unexpected bissilylation and unforeseen regioselectivity.

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@article{Auer2006SilylzincationOC, title={Silylzincation of carbon-carbon multiple bonds revisited.}, author={Gertrud Auer and Martin Oestreich}, journal={Chemical communications}, year={2006}, volume={3}, pages={311-3} }