Silyl ligand mediated reversible β-hydrogen elimination and hydrometalation at palladium.

Abstract

The mechanism and origin of the facile β-hydrogen elimination and hydrometalation of a palladium complex bearing a phenylene-bridged PSiP pincer ligand are clarified. Experimental and theoretical studies demonstrate a new mechanism for β-hydrogen elimination and hydrometalation mediated by a silyl ligand at palladium, which enables direct interconversion… (More)
DOI: 10.1002/chem.201403220

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Cite this paper

@article{Takaya2014SilylLM, title={Silyl ligand mediated reversible β-hydrogen elimination and hydrometalation at palladium.}, author={Jun Takaya and Nobuharu Iwasawa}, journal={Chemistry}, year={2014}, volume={20 37}, pages={11812-9} }