Silver and thallium(I) complexation with dibenzo-16-crown-4.

@article{Ouchi1999SilverAT,
  title={Silver and thallium(I) complexation with dibenzo-16-crown-4.},
  author={M. Ouchi and Y. Shibutani and K. Yakabe and T. Shono and H. Shintani and A. Yoneda and T. Hakushi and E. Weber},
  journal={Bioorganic \& medicinal chemistry},
  year={1999},
  volume={7 6},
  pages={
          1123-6
        }
}
Dibenzo-16-crown-4 (1) indicates high silver and thallium(I) ion selectivity over sodium, potassium, and rubidium ion evaluated from the solvent extraction of metal picrates, while its cation-binding ability is lower than those of dibenzo-18-crown-6 (2) and dibenzo-22-crown-6 (3). Taking account of the highest thallium(I) ion selectivity for 1 obtained from extraction experiments, PVC membrane thallium(I)-selective electrodes based on 1 are prepared. The electrode shows the best potentiometric… Expand
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