Side-on bridging coordination of N2: spectroscopic characterization of the planar Zr2N2 core and theoretical investigation of its butterfly distortion.

Abstract

The vibrational and electronic structure of the side-on N(2)-bridged Zr complex [((P(2)N(2))Zr)(2)(mu-eta(2):eta(2)-N(2))] (P(2)N(2)=PhP(CH(2)SiMe(2)NSiMe(2)CH(2))(2)PPh) were analyzed. The vibrational characterization of the planar Zr(2)N(2) core was based on resonance Raman and infrared spectroscopy. In the Raman spectrum, the Nbond;N stretching band is… (More)

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