Sequential dielectric phase transitions induced by the vibrations of water molecules in an organic-inorganic hybrid halide (N-(2-ammoniumethyl)piperazinium) CuCl5·2H2O.

@article{Wang2017SequentialDP,
  title={Sequential dielectric phase transitions induced by the vibrations of water molecules in an organic-inorganic hybrid halide (N-(2-ammoniumethyl)piperazinium) CuCl5·2H2O.},
  author={Zhongxia Wang and Yang Lu and Zainab Zafar and Yu-Ling Liu and Hai-Peng Chen and Jia-Zhen Ge},
  journal={Dalton transactions},
  year={2017},
  volume={46 31},
  pages={
          10462-10468
        }
}
Organic-inorganic hybrids represent a new type of material showing promising properties. In this report, sequential dielectric transitions have been studied in an organic-inorganic hybrid halide, (N-2-AP)CuCl5·2H2O (N-2-AP = N-(2-ammoniumethyl)piperazinium) (1). The packing structure of 1 displays discrete [CuCl5]3- rectangular pyramids and N-2-AP cations, which are linked by two water molecules, forming infinite hydrogen bond networks with inorganic and organic components along the b-axis… 
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