Separation of non-racemic mixtures of enantiomers: an essential part of optical resolution.

@article{Faigl2010SeparationON,
  title={Separation of non-racemic mixtures of enantiomers: an essential part of optical resolution.},
  author={Ferenc Faigl and Elem{\'e}r Fogassy and Mih{\'a}ly N{\'o}gr{\'a}di and Emese P{\'a}lovics and J{\'o}zsef Schindler},
  journal={Organic & biomolecular chemistry},
  year={2010},
  volume={8 5},
  pages={947-59}
}
Non-racemic enantiomeric mixtures form homochiral and heterochiral aggregates in melt or suspension, during adsorption or recrystallization, and these diastereomeric associations determine the distribution of the enantiomers between the solid and other (liquid or vapour) phases. That distribution depends on the stability order of the homo- and heterochiral… CONTINUE READING