Separating para and ortho water.
@article{Horke2014SeparatingPA, title={Separating para and ortho water.}, author={Daniel A. Horke and Yuan-Pin Chang and Karol Długołȩcki and Jochen K{\"u}pper}, journal={Angewandte Chemie}, year={2014}, volume={53 44}, pages={ 11965-8 } }
Water exists as two nuclear-spin isomers, para and ortho, determined by the overall spin of its two hydrogen nuclei. For isolated water molecules, the conversion between these isomers is forbidden and they act as different molecular species. Yet, these species are not readily separated, and no pure para sample has been produced. Accordingly, little is known about their specific physical and chemical properties, conversion mechanisms, or interactions. The production of isolated samples of both…
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References
SHOWING 1-10 OF 37 REFERENCES
A Magnetically Focused Molecular Beam of Ortho-Water
- PhysicsScience
- 2011
The formation of a magnetically focused molecular beam of ortho-water, where the water molecules are hyperpolarized, laying the foundation for ultrasensitive NMR experiments in the future.
Nuclear spin conversion in polyatomic molecules.
- Chemistry, PhysicsAnnual review of physical chemistry
- 1999
Detailed data on CH3F reveal that the gas-phase ortho-para conversion is governed by intramolecular mixing of the nuclear spin states, and the most decisive information is derived from the observation of level-crossing resonances in an electric field and the quantum Zeno effect induced by collisions.
Mechanisms of Dipolar Ortho/Para-H2O Conversion in Ice
- Physics
- 2008
Abstract In this paper a possible explanation for an unexpected ortho/para-water ratio in the gas clouds of comets is given. The description is based on the quantum-mechanical density matrix…
Separation and Conversion Dynamics of Four Nuclear Spin Isomers of Ethylene
- Physics, ChemistryScience
- 2005
The results suggest a spin conversion mechanism in C2H4 via quantum relaxation within the same inversion symmetry in B2u and B3u isomers at a rate linearly proportional to pressure, with almost no change in the Ag isomer populations.
Novel insights into the mechanism of the ortho/para spin conversion of hydrogen pairs: implications for catalysis and interstellar water.
- PhysicsChemphyschem : a European journal of chemical physics and physical chemistry
- 2006
It is shown that the exchange coupling needs to be reduced so that the corresponding exchange barrier can increase and the given magnetic interaction can effectively induce a spin conversion, which means a separation of water into its spin isomers is not feasible.
Pure samples of individual conformers: the separation of stereoisomers of complex molecules using electric fields.
- Physics, ChemistryAngewandte Chemie
- 2009
It is demonstrated that electrostatic deflection, a classic molecular beam manipulation method that dates back to the 1920s, allows the spatial separation of the conformers of a neutral molecule when it is applied to intense beams of rotationally cold molecules produced by a state-ofthe-art pulsed supersonic expansion source.
On the possibility of enrichment of H2O nuclear spin isomers by adsorption
- Chemistry
- 2006
Experimental data on the enrichment of H2O nuclear spin isomers by means of adsorption, as suggested in several works by other authors, are reported. We were unable to observe any enrichment of…
Nuclear spin symmetry conservation and relaxation in water ((1)H2(16)O) studied by cavity ring-down (CRD) spectroscopy of supersonic jets.
- PhysicsThe journal of physical chemistry. A
- 2013
The nuclear spin symmetry relaxation observed is seen to be related to the formation of water clusters at the early stage of the supersonic jet expansion, which cannot be explained by the intramolecular quantum relaxation mechanism in the monomer H2O.
Nuclear Spin State Equilibration through Nonmagnetic Collisions
- Physics, Chemistry
- 1967
For nonlinear molecules with equivalent identical nuclei an important pathway leading to equilibration of nuclear spin statistics isomers is provided by wavefunction mixing induced by the…
Observation of Ortho-Para {bold H}{sup {bold +}}{sub {bold 3}} Selection Rules in Plasma Chemistry
- Physics
- 1997
Intensity ratios of infrared spectral lines of ortho- and para-H{sup +}{sub 3} have been measured in hydrogen plasmas using normal and para-H{sub 2}. Large dependences of the intensity ratios on the…