Semi-empirical branching fractions of the 3 s 23 p 2 – 3 s 3 p 3 J = 2 transition array in P II 1

Abstract

A semi-empirical method is used to characterize the 3s23p2–3s3p3 J = 2 transition array in P II. In this method Slater, spin–orbit, and radial parameters are fitted to experimental energy levels to obtain a description of the array in terms of LS-coupling basis vectors. The intermediate coupling (IC) and configuration interaction (CI) amplitudes so obtained… (More)

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