Self-organizing oligothiophene-nucleoside conjugates: versatile synthesis via "click"-chemistry.

Abstract

A versatile synthesis of novel oligothiophene-nucleoside conjugates based on Cu(I)-catalyzed alkyne-azide cycloaddition ("click-reaction") has been developed. Complementary thymidine- and adenosine-functionalized quaterthiophenes form recognition-driven superstructures via hydrogen bonding and other competing intermolecular forces. Self-aggregated fibers up… (More)
DOI: 10.1021/ol703090f

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