Self-healing kinetics and the stereoisomers of dicyclopentadiene.

@article{Mauldin2007SelfhealingKA,
  title={Self-healing kinetics and the stereoisomers of dicyclopentadiene.},
  author={Timothy C. Mauldin and Joseph D. Rule and Nancy R. Sottos and Scott R. White and Jeffrey S. Moore},
  journal={Journal of the Royal Society, Interface},
  year={2007},
  volume={4 13},
  pages={389-93}
}
While original epoxy resin-based self-healing systems used the commercially available endo-isomer of dicyclopentadiene (DCPD), the exo-stereoisomer is known to have much faster olefin metathesis reaction rates with first-generation Grubbs' catalyst. Here, we measure the energy to failure of healed specimens as a function of healing time and compare the kinetics of damage repair for endo- and exo-DCPD, and mixtures of the two isomers. Using catalyst loading levels previously reported to be… CONTINUE READING
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