Self-assembly of luminescent N-annulated perylene tetraesters into fluid columnar phases.


A new class of N-annulated perylene tetraesters and their N-alkylated derivatives has been synthesized. N-Annulated perylene tetraesters stabilize a hexagonal columnar phase over a broad temperature range. The hexagonal columnar phase exhibited by these compounds shows good homeotropic alignment with few defects. Annulation in the bay region of the perylene… (More)
DOI: 10.1039/c5sm00463b


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