Self-assembled monolayer of a peroxo-bridged dinuclear cobalt(III) complex on Au(111).

Abstract

Densely packed Self-Assembled Monolayers (SAMs) of a peroxide-bridged dicobalt complex, [Co2(O2)(bpbp)(O2CCH2CH2S)]2+, 3, (bpbp- = 2,6-bis((N,N-bis-(2-picolyl)amino)-methyl)-4-tert-butylphenolato) have been prepared on atomically planar Au(111) surfaces. Surface voltammetric and interfacial capacitance data, along with electrochemical scanning tunnelling… (More)

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