Self- and cross-reactions of β-hydroxyperoxy radicals of relevance to tropospheric monoterpene oxidation: structure–activity relationships for rate coefficients

@inproceedings{Boyd2003SelfAC,
  title={Self- and cross-reactions of β-hydroxyperoxy radicals of relevance to tropospheric monoterpene oxidation: structure–activity relationships for rate coefficients},
  author={Andrew A. Boyd and Eric Villenave and Robert Lesclaux},
  year={2003}
}
Abstract The laser flash photolysis technique has been used to measure rate coefficients for the self- and cross-reactions of four peroxy radicals, which have been selected as surrogate of those peroxy radicals resulting from the OH addition to monoterpenes: the 2-hydroxycyclohexylperoxy c- C 6 H 10 (OH)O 2 (I), 2-hydroxy-1,2-dimethylcyclohexylperoxy c- C 6 H 8 (CH 3 ) 2 (OH)O 2 (II), 2-hydroxy-2-methylcyclohexylperoxy c- C 6 H 9 (OH)CH 3 O 2 (III) and 2-hydroxy-1-methylcyclohexylperoxy c- C 6… CONTINUE READING