Selective removal of metallic single-walled carbon nanotubes with small diameters by using nitric and sulfuric acids.

@article{Yang2005SelectiveRO,
  title={Selective removal of metallic single-walled carbon nanotubes with small diameters by using nitric and sulfuric acids.},
  author={C Yang and Jin Sung Park and Kay Hyeok An and Seong Chu Lim and Kwanyong Seo and B. F. Kim and Kyung Ah Park and Seungwu Han and Chong Yun Park and Young Hee Lee},
  journal={The journal of physical chemistry. B},
  year={2005},
  volume={109 41},
  pages={19242-8}
}
Coexistence of metallic and semiconducting carbon nanotubes has often been a bottleneck in many applications and much fundamental research. Single-walled carbon nanotubes (SWCNTs) were dissolved in HNO3/H2SO4 mixture to confirm differing reactivity between metallic (m) and semiconducting (s) SWCNTs. With HNO3/H2SO4 treatment, s-SWCNTs remained intact, while m-SWCNTs were completely removed for SWCNTs with small diameters less than 1.1 nm, which was confirmed by resonant Raman and optical… CONTINUE READING
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