Selective oxidation at carbon adjacent to aromatic systems with IBX.

@article{Nicolaou2001SelectiveOA,
  title={Selective oxidation at carbon adjacent to aromatic systems with IBX.},
  author={Kyriacos C Nicolaou and Phil S Baran and Yuzuo Zhong},
  journal={Journal of the American Chemical Society},
  year={2001},
  volume={123 13},
  pages={
          3183-5
        }
}
Recei Ved December 5, 2000 A number of new synthetic technologies based on the reactivity of the periodinane reagents DMP and IBX have recently been reported from these laboratories. 1 These reactions include the IBXinduced cyclization of unsaturated anilides (Figure 1A), 1b whose single-electron transfer (SET) mechanism was recently elucidated, 2 and the introduction of unsaturation next to carbonyl groups, 1d now also believed to proceed, by analogy, via a SET mechanism (Figure 1B). On the… CONTINUE READING
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