Selective iron-catalyzed transfer hydrogenation of terminal alkynes.

@article{Wienhoefer2012SelectiveIT,
  title={Selective iron-catalyzed transfer hydrogenation of terminal alkynes.},
  author={Gerrit Wienhoefer and Felix Alexander Westerhaus and Rajenahally V. Jagadeesh and Kathrin Junge and Henrik Junge and Matthias Beller},
  journal={Chemical communications},
  year={2012},
  volume={48 40},
  pages={
          4827-9
        }
}
A novel iron-catalyzed transfer hydrogenation of alkynes to the corresponding alkenes applying formic acid as a hydrogen donor is reported. An in situ combination of Fe(BF(4))(2)·6H(2)O and tetraphos allows for highly selective hydrogenation of a broad range of aromatic and aliphatic alkynes tolerating different functional groups. 
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