Selective hydration of alkylammonium ions in nitrobenzene

@article{Ogata2000SelectiveHO,
  title={Selective hydration of alkylammonium ions in nitrobenzene},
  author={Akiko Ogata and Yoshio Tsujino and Toshiyuki Osakai},
  journal={Physical Chemistry Chemical Physics},
  year={2000},
  volume={2},
  pages={247-251}
}
In the nitrobenzene (NB)/water system, primary to tertiary ammonium ions with Me, Et and n-Bu groups were distributed with dipicrylaminate (DPA−) and tetraphenylborate (TPB−), and the number of water molecules being co-extracted to NB by an alkylammonium ion (RmNH4−m+) was measured by the Karl Fischer method. In the use of TPB− as the counter ion, the numbers of co-extracted water molecules, mainly for primary and secondary alkylammonium ions, were somewhat smaller than those in the use… Expand
6 Citations
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