Secondary hypervalent I(III)...O interactions: synthesis and structure of hypervalent complexes of diphenyl-lambda3-iodanes with 18-crown-6.

Abstract

Reported here for the first time are the synthesis and characterization of supramolecular complexes between diaryl-lambda(3)-iodanes and 18-crown-6 (18C6). Slow evaporation of solvents afforded 1:1 and 2:1 complexes between Ph(2)IBF(4) and 18C6 as stable crystals, depending on the conditions. X-ray crystal structures of these complexes indicated that each… (More)

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Cite this paper

@article{Ochiai2003SecondaryHI, title={Secondary hypervalent I(III)...O interactions: synthesis and structure of hypervalent complexes of diphenyl-lambda3-iodanes with 18-crown-6.}, author={Masahito Ochiai and Takashi Suefuji and Kazunori Miyamoto and Norihiro Tada and Satoru Goto and Motoo Shiro and S. Sakamoto and Kentaro Yamaguchi}, journal={Journal of the American Chemical Society}, year={2003}, volume={125 3}, pages={769-73} }