Scanning tunnelling microscopy of suspended graphene.

@article{Zan2012ScanningTM,
  title={Scanning tunnelling microscopy of suspended graphene.},
  author={Recep Zan and Christopher A Muryn and Ursel Bangert and Philip W. Mattocks and Paul L. Wincott and David Vaughan and Xuesong Li and Luigi Pietro Maria Colombo and Rodney S. Ruoff and B. Hamilton and Kostya S. Novoselov},
  journal={Nanoscale},
  year={2012},
  volume={4 10},
  pages={
          3065-8
        }
}
Suspended graphene has been studied by STM for the first time. Atomic resolution on mono- and bi-layer graphene samples has been obtained after ridding the graphene surface of contamination via high-temperature annealing. Static local corrugations (ripples) have been observed on both types of structures. 

Figures from this paper

Microscopic characterisation of suspended graphene grown by chemical vapour deposition.
TLDR
It is demonstrated that the suspended graphene membrane locally shows electronic properties comparable with those of samples prepared by micromechanical cleaving of graphite, and the area of high quality suspended graphene is limited by the folding of the graphene during the transfer.
Residue reduction and intersurface interaction on single graphene sheets
Limitations of the Fluorination of Graphene on a Substrate
The experimentally observed incomplete fluorination of graphene (CFx, x ≤ 0.2−0.3) on a smooth substrate has been explained. It has been shown that fluorine atoms are covalently attached primarily to
Probing Electronic Properties of Graphene on the Atomic Scale by Scanning Tunneling Microscopy and Spectroscopy
Atomic scale investigations of the electronic properties of graphene are playing a crucial role in understanding and tuning the exotic properties of this material for its potential device
Atomic-Scale Characterization and Manipulation of Freestanding Graphene Using Adapted Capabilities of a Scanning Tunneling Microscope
Graphene was the first two-dimensional material ever discovered, and it exhibits many unusual phenomena important to both pure and applied physics. To ensure the purest electronic structure, or to
Determination of the STM tip-graphene repulsive forces by comparative STM and AFM measurements on suspended graphene
Graphene grown by chemical vapour deposition is transferred on top of flat gold nanoislands and characterized by scanning tunnelling microscopy (STM) and atomic force microscopy (AFM). Graphene
Apparent rippling with honeycomb symmetry and tunable periodicity observed by scanning tunneling microscopy on suspended graphene
Suspended graphene is difficult to image by scanning probe microscopy due to the inherent van-der-Waals and dielectric forces exerted by the tip which are not counteracted by a substrate. Here, we
Mirror Buckling Transitions in Freestanding Graphene Membranes Induced through Scanning Tunneling Microscopy
Graphene has the ability to provide for a technological revolution. First isolated and characterized in 2004, this material shows promise in the field of flexible electronics. The electronic
Rotated domain network in graphene on cubic-SiC(001).
TLDR
The presented data show the correlation between the atomic structures of the SiC(001)-c(2 × 2) surface and the graphene/SiC(002) rotated domain network and pave the way for optimizing large-area graphene synthesis on low-cost cubic-SiC (001)/Si(001) wafers.
Self-organized platinum nanoparticles on freestanding graphene.
TLDR
High-resolution transmission electron microscopy revealed a homogeneous distribution of single-crystal Pt NPs that tend to exhibit a preferred orientation that is expected to shape future approaches in developing Pt NP catalysts for fuel cells as well as NP-functionalized graphene-based high-performance electronics.
...
1
2
3
4
5
...

References

SHOWING 1-10 OF 58 REFERENCES
Epitaxial graphene on Cu(111).
TLDR
Results reveal that reducing the density of domain boundaries is one challenge of growing high-quality graphene on copper.
Atomic structure of graphene on SiO2.
TLDR
Atomic structures and nanoscale morphology of graphene-based electronic devices are revealed for the first time and a strong spatially dependent perturbation is revealed which breaks the hexagonal lattice symmetry of the graphitic lattice.
Surface intercalation of gold underneath a graphene monolayer on SiC(0001) studied by scanning tunneling microscopy and spectroscopy
The effects of gold deposition on monolayer graphene (MG) epitaxied on SiC (0001) substrate are examined via scanning tunneling microscopy and scanning tunneling spectroscopy (STS). Two types of
Giant Surface Charge Density of Graphene Resolved From Scanning Tunneling Microscopy and First-Principles Theory
In this work, systematic constant-bias, variable-current scanning tunneling microscopy (STM) measurements and STM simulations from density-functional theory are made, yielding critical insights into
High-resolution scanning tunneling microscopy imaging of mesoscopic graphene sheets on an insulating surface
TLDR
Scan scanning tunneling microscopy (STM) images of single-layer graphene crystals examined under ultrahigh vacuum conditions display the honeycomb structure expected for the full hexagonal symmetry of an isolated graphene monolayer.
Electron states of mono and bilayer graphene on SiC probed by scanning-tunneling microscopy
We present a scanning tunneling microscopy (STM) study of a gently-graphitized 6H-SiC(0001) surface in ultra high vacuum. From an analysis of atomic scale images, we identify two different kinds of
Intrinsic and extrinsic corrugation of monolayer graphene deposited on SiO2.
TLDR
A detailed analysis shows that the long-range corrugation of the substrate is also visible on graphene, but with a reduced amplitude, leading to the conclusion that the graphene is partly freely suspended between hills of the substrates.
Two-dimensional Ir cluster lattice on a graphene moiré on Ir(111).
TLDR
A model for cluster binding to the graphene is presented based on scanning tunneling microscopy and density functional theory, which suggests that similar cluster lattices might be grown of materials other than Ir.
Electronic structure of epitaxial graphene layers on SiC: effect of the substrate.
TLDR
The graphene is doped and a gap opens at the Dirac point after three Bernal stacked carbon layers are formed and evidence of a charge transfer that depends on the interface geometry is presented.
Scanning tunneling spectroscopy of graphene on graphite.
We report low temperature high magnetic field scanning tunneling microscopy and spectroscopy of graphene flakes on graphite that exhibit the structural and electronic properties of graphene decoupled
...
1
2
3
4
5
...