Scandium-catalyzed carbon-carbon bond formations using alpha-organosulfanyl and organoselanyl-alpha-fluoroacetic acid derivatives.

Abstract

The scandium-catalyzed reactions of alpha-organosulfanyl and organoselanyl-alpha-fluoroacetates 1-2, acetamides 3-4 and acetonitrile 5 with soft nucleophiles proceeded to give the products 6a-b, 7a-c, 8a-c, 9a-e in good to high yields. We also successfully performed the scandium-catalyzed intramolecular cyclization reactions and obtained the unique 5… (More)

Topics

Cite this paper

@article{Gotoh2006ScandiumcatalyzedCB, title={Scandium-catalyzed carbon-carbon bond formations using alpha-organosulfanyl and organoselanyl-alpha-fluoroacetic acid derivatives.}, author={Kohei Gotoh and Teruhisa Yamamoto and Mitsuhiro Yoshimatsu}, journal={Chemical & pharmaceutical bulletin}, year={2006}, volume={54 11}, pages={1611-5} }