Sample dimensionality: a predictor of order-disorder in component peak distribution in multidimensional separation.

@article{Giddings1995SampleDA,
  title={Sample dimensionality: a predictor of order-disorder in component peak distribution in multidimensional separation.},
  author={J. Calvin Giddings},
  journal={Journal of chromatography. A},
  year={1995},
  volume={703 1-2},
  pages={
          3-15
        }
}
While the use of multiple dimensions in separation systems can create very high peak capacities, the effectiveness of the enhanced peak capacity in resolving large numbers of components depends strongly on whether the distribution of component peaks is ordered or disordered. Peak overlap is common in disordered distributions, even with a very high peak capacity. It is therefore of great importance to understand the origin of peak order/disorder in multidimensional separations and to address the… CONTINUE READING
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