STEREOSELECTIVE OXIDATION OF AN ELEVEN - MEMBERED HETEROCYCLE Paul

Abstract

Oxidation of macrocyclic phosphine oxide-dithioether 1 produces only the dl form of disulfoxide 2. This selectivity can be rationalized by comparing the crystal structures of starting material and product, and on the basis of VT NMR data, which suggest that the starting macrocycle is conformationally constrained in solution. Molecules containing multiple… (More)

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@inproceedings{SavageSTEREOSELECTIVEOO, title={STEREOSELECTIVE OXIDATION OF AN ELEVEN - MEMBERED HETEROCYCLE Paul}, author={P B Savage and John M. Desper and Samuel H. Gellman} }