Ruthenium nitrosyls derived from tetradentate ligands containing carboxamido-N and phenolato-o donors: syntheses, structures, photolability, and time dependent density functional theory studies.

@article{Fry2010RutheniumND,
  title={Ruthenium nitrosyls derived from tetradentate ligands containing carboxamido-N and phenolato-o donors: syntheses, structures, photolability, and time dependent density functional theory studies.},
  author={Nicole Lynn Fry and Michael J Rose and David L. Rogow and Crystal Evie Nyitray and Manpreet Kaur Manpreet Kaur and Pradip K Mascharak},
  journal={Inorganic chemistry},
  year={2010},
  volume={49 4},
  pages={
          1487-95
        }
}
In order to examine the role(s) of designed ligands on the NO photolability of {Ru-NO}(6) nitrosyls, a set of three nitrosyls with ligands containing two carboxamide groups along with a varying number of phenolates have been synthesized. The nitrosyls namely, (NEt(4))(2)[(hybeb)Ru(NO)(OEt)] (1), (PPh(4))[(hypyb)Ru(NO)(OEt)] (2), and [(bpb)Ru(NO)(OEt)] (3) have been characterized by X-ray crystallography. Complexes 1-3 are diamagnetic, exhibit nu(NO) in the range 1780-1840 cm(-1) and rapidly… CONTINUE READING
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The photochemistry of transition metal complexes using density functional theory.

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