Ruthenium based catalysts for olefin hydrosilylation: dichloro(p-cymene)ruthenium and related complexes.

@article{Tuttle2009RutheniumBC,
  title={Ruthenium based catalysts for olefin hydrosilylation: dichloro(p-cymene)ruthenium and related complexes.},
  author={Tell Tuttle and Dongqi Wang and Walter Thiel and Jutta E. H. K{\"o}hler and Marco Hofmann and Johann Weis},
  journal={Dalton transactions},
  year={2009},
  volume={30},
  pages={
          5894-901
        }
}
We report our third and final investigation into the use of ruthenium based compounds for catalyzing the hydrosilylation of methylvinyldimethoxysilane with methyldimethoxysilane. The catalytic mechanism of dichloro(p-cymene)ruthenium(II) (B1) is examined and compared to that of previously studied, less active catalysts. Density functional theory (DFT) has been applied to explore the possibility of fine-tuning the catalytic ability of B1. The eta(6)-ligand and the sigma-donor ligands were varied… Expand
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