Ru(III)(EDTA) mediated S-nitrosylation of cysteine by nitrite.

Abstract

Reported here is the first example of a ruthenium(iii) complex [Ru(III)(EDTA)(H2O)](-) (EDTA(4-) = ethylenediaminetetraacetate) that mediates S-nitrosylation of cysteine in the presence of nitrite at pH 4.5 (acetate buffer) and results in the formation of [Ru(III)(EDTA)(SNOCy)](-). The kinetics of the reaction was studied by stopped-flow and rapid-scan… (More)
DOI: 10.1039/c4dt02628d

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@article{Chatterjee2014RuIIIEDTAMS, title={Ru(III)(EDTA) mediated S-nitrosylation of cysteine by nitrite.}, author={Debabrata Chatterjee and Namita Jaiswal and Matthias Schmeisser and Rudi van Eldik}, journal={Dalton transactions}, year={2014}, volume={43 48}, pages={18042-6} }