Ru(II), Os(II), and Ir(III) complexes with chelating pyridyl-mesoionic carbene ligands: structural characterization and applications in transfer hydrogenation catalysis.

@article{Bolje2015RuIIOA,
  title={Ru(II), Os(II), and Ir(III) complexes with chelating pyridyl-mesoionic carbene ligands: structural characterization and applications in transfer hydrogenation catalysis.},
  author={A. Bolje and S. Hohloch and Margarethe van der Meer and J. Ko{\vs}mrlj and B. Sarkar},
  journal={Chemistry},
  year={2015},
  volume={21 18},
  pages={
          6756-64
        }
}
Chelating ligands with one pyridine donor and one mesoionic carbene donor are fast establishing themselves as privileged ligands in homogeneous catalysis. The synthesis of several new Ir(III)-Cp*- and Os(II)-Cym complexes (Cp* = pentamethylcyclopentadienyl, Cym = p-cymene=4-isopropyl-toluene) derived from chelating pyridyltriazolylidenes where the additional pyridine donor was incorporated via the azide part of the triazole is presented. Furthermore, different 4-substituted phenylacetylene… Expand
A Mesoionic Carbene as Neutral Ligand for Phosphorescent Cationic Ir(III) Complexes.
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