Rovibrational dynamics of the strontium molecule in the A(1)Σ(u)+, c(3)Π(u), and a(3)Σ(u)+ manifold from state-of-the-art ab initio calculations.

  title={Rovibrational dynamics of the strontium molecule in the A(1)$\Sigma$(u)+, c(3)$\Pi$(u), and a(3)$\Sigma$(u)+ manifold from state-of-the-art ab initio calculations.},
  author={Wojciech Skomorowski and Filip Pawłowski and Christiane P. Koch and Robert Moszynski},
  journal={The Journal of chemical physics},
  volume={136 19},
State-of-the-art ab initio techniques have been applied to compute the potential energy curves for the electronic states in the A(1)Σ(u)(+), c(3)Π(u), and a(3)Σ(u)(+) manifold of the strontium dimer, the spin-orbit and nonadiabatic coupling matrix elements between the states in the manifold, and the electric transition dipole moment from the ground X(1)Σ(g)(+) to the nonrelativistic and relativistic states in the A+c+a manifold. The potential energy curves and transition moments were obtained… 
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