Role of electronegativity in the qualitative inference of the TOF-SIMS fragment pattern of inorganic compounds.


The role of the electronegativity of atoms in inorganic compounds in TOF-SIMS fragmentation is discussed. From a study of approximately 30 inorganic compounds--chlorides, oxides, nitrates, and sulfates--a simple rule has been proposed for the dependence of fragment pattern appearance on the electronegativity (electron affinity), which can be easily obtained… (More)


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