Rhodium catalyzed chelation-assisted C-H bond functionalization reactions.

@article{Colby2012RhodiumCC,
  title={Rhodium catalyzed chelation-assisted C-H bond functionalization reactions.},
  author={D. A. Colby and A. Tsai and R. G. Bergman and J. Ellman},
  journal={Accounts of chemical research},
  year={2012},
  volume={45 6},
  pages={
          814-25
        }
}
Over the last several decades, researchers have achieved remarkable progress in the field of organometallic chemistry. The development of metal-catalyzed cross-coupling reactions represents a paradigm shift in chemical synthesis, and today synthetic chemists can readily access carbon-carbon and carbon-heteroatom bonds from a vast array of starting compounds. Although we cannot understate the importance of these methods, the required prefunctionalization to carry out these reactions adds cost… Expand
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