Revised hydrolysis constants for thallium(I) and thallium(III) and the environmental implications.


The hydrolysis constants for Tl(I) and Tl(III) have been determined by combining potentiometric measurement with the PKAS computer program. The log hydrolysis constants (Khi) for Tl(I)(OH)i-1i + H2O<==>Tl(I) (OH)i1-i + H+ have been determined to be -11.7, and those for Tl(III)(OH)i-1(4-i) + H2O<==>Tl(III)(OH)i3-i + H+ are -2.69, -6.36, -7.42, and -8.78… (More)


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