Reversible Structural Changes Accompanying the Two-Electron Redox Reaction of Pt(tacn) (tacn: 1,4,7-triazacyclononane) Complexes

@article{Wada2015ReversibleSC,
  title={Reversible Structural Changes Accompanying the Two-Electron Redox Reaction of Pt(tacn) (tacn: 1,4,7-triazacyclononane) Complexes},
  author={Tohru Wada and Koki Enami and Ryohei Kojima and Tomoki Okada and Yuki Ishikawa and Yuji Miyazato and Ernst Horn and Yuji Mochizuki},
  journal={Bulletin of the Chemical Society of Japan},
  year={2015},
  volume={88},
  pages={1230-1237}
}
Platinum complexes with 1,4,7-triazacyclononane (tacn) as facial ligands, [PtIVCl3(tacn)](ClO4), [PtIVCl(bpy)(tacn)](ClO4)3 ([1](ClO4), and [2](ClO4)3, bpy: 2,2′-bipyridine) were prepared, and thei... 
1 Citations
Side Reactions with an Equilibrium Constraint: Detailed Mechanism of the Substitution Reaction of Tetraplatin with dGMP as a Starting Step of the Platinum(IV) Reduction Process.
Two possible pathways of the substitution reaction within the reduction process of the PtIV(DACH)Cl4 by dGMP are compared: associative reaction course and autocatalytic Basolo-Pearson mechanisms.

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