Reversible Insertion of Methyl Isothiocyanate into Copper(I) Aryloxides.


MeNCS undergoes insertion into the copper(I)-aryloxide bond to form [N-methylimino(aryloxy)methanethiolato]copper(I) complexes. This insertion occurs in the absence of ancillary ligands unlike the analogous insertion of PhNCS. The reaction with 4-methylphenoxide results in the formation of hexakis[[N-methylimino(4-methylphenoxy)methanethiolato]copper(I)] (1… (More)


Figures and Tables

Sorry, we couldn't extract any figures or tables for this paper.