Reversible Capture and Release of Cl2 and Br2 with a Redox-Active Metal-Organic Framework.

@article{Tulchinsky2017ReversibleCA,
  title={Reversible Capture and Release of Cl2 and Br2 with a Redox-Active Metal-Organic Framework.},
  author={Yuri Tulchinsky and Christopher H Hendon and Kirill A Lomachenko and Elisa Borfecchia and Brent C Melot and Matthew R. Hudson and Jacob D Tarver and Maciej D Korzyński and Amanda W. Stubbs and Jacob J Kagan and Carlo Lamberti and Craig M Brown and Mircea Dincă},
  journal={Journal of the American Chemical Society},
  year={2017},
  volume={139 16},
  pages={5992-5997}
}
Extreme toxicity, corrosiveness, and volatility pose serious challenges for the safe storage and transportation of elemental chlorine and bromine, which play critical roles in the chemical industry. Solid materials capable of forming stable nonvolatile compounds upon reaction with elemental halogens may partially mitigate these challenges by allowing safe… CONTINUE READING