Retention Behavior of Halogenated Benzenes on a Stationary Phase Having a 2,4-Dibromophenoxy Group as the Halogen Recognition Functional Group.

@article{Miwa2015RetentionBO,
  title={Retention Behavior of Halogenated Benzenes on a Stationary Phase Having a 2,4-Dibromophenoxy Group as the Halogen Recognition Functional Group.},
  author={Toshio Miwa and Shiho Suzuki and Rina Takai and Ryohei Yamamoto and Yoshinori Inoue and Atsushi Yamamoto},
  journal={Analytical sciences : the international journal of the Japan Society for Analytical Chemistry},
  year={2015},
  volume={31 8},
  pages={841-5}
}
A stationary phase with a dipole interaction was synthesized by immobilizing the 2,4-dibromophenoxy (DBP) group onto a hydrophilic base resin. The chromatographic properties for halogenated benzenes were evaluated on the DBP-resin by reversed phase mode. The separation efficiency of the DBP-resin for p-xylene and 1,4-dihalogenated benzenes was better than that of the column packed with octadecylsilane (ODS). The results suggested that the retention of the solutes on the DBP-resin depends on the… CONTINUE READING

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