Resonance Raman spectra of octaethylporphyrinato‐Ni(II) and meso‐deuterated and 15N substituted derivatives. I. Observation and assignments of nonfundamental Raman lines

@article{Kitagawa1978ResonanceRS,
  title={Resonance Raman spectra of octaethylporphyrinato‐Ni(II) and meso‐deuterated and 15N substituted derivatives. I. Observation and assignments of nonfundamental Raman lines},
  author={T. Kitagawa and M. Abe and H. Ogoshi},
  journal={Journal of Chemical Physics},
  year={1978},
  volume={69},
  pages={4516-4525}
}
High resolution resonance Raman spectra of octaethylporphyrinato‐Ni(II) [Ni (OEP)], its meso‐deuterated and 15N substituted derivatives were measured. With excitation near the O–1 transition, about 90 nonfundamental modes and previously unrecognized fundamental modes were observed for each derivative. The analysis of the nonfundamental Raman lines allowed the determination of all the fundamental frequencies in the A1g, B1g, A2g, and B2g species of D4h symmetry. Experimental classification of… Expand
Theoretical study of the resonance Raman spectra for meso-tetrakis(3,5-di-tertiarybutylphenyl)-porphyrin.
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