Resolution of P-stereogenic P-heterocycles via the formation of diastereomeric molecular and coordination complexes (a review).

Abstract

TADDOL derivatives and the Ca(2+)-salts of tartaric acid derivatives were found to be versatile and generally applicable resolving agents for the preparation of the enantiomers of P-stereogenic heterocyclic phosphine oxides and phosphinates via the formation of the corresponding diastereomeric molecular and coordination complexes. A few of the… (More)
DOI: 10.1039/c5dt02999f

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