Remarkable effect of iridium cyclometalation on the nonlinear absorption properties of a quadrupolar imine ligand.

Abstract

A new type of dinuclear iridium complex, based on a quadrupolar Schiff base ligand, is synthesized and its structure fully characterized. Its linear and nonlinear spectroscopic properties are investigated, evidencing a strong contribution of the metal-to-ligand transitions not only to the linear absorption but also to the two- and three-photon absorption… (More)
DOI: 10.1021/ic4012313

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@article{Massue2013RemarkableEO, title={Remarkable effect of iridium cyclometalation on the nonlinear absorption properties of a quadrupolar imine ligand.}, author={Julien Massue and Joanna Olesiak-Banska and Erwann Jeanneau and Christophe Aronica and Katarzyna Matczyszyn and Marek Samo{\'c} and Cyrille Monnereau and Chantal Andraud}, journal={Inorganic chemistry}, year={2013}, volume={52 19}, pages={10705-7} }