Remarkable Lattice Shrinkage in Highly Oriented Crystalline Three-Dimensional Metal-Organic Framework Thin Films.

@article{Haraguchi2015RemarkableLS,
  title={Remarkable Lattice Shrinkage in Highly Oriented Crystalline Three-Dimensional Metal-Organic Framework Thin Films.},
  author={Tomoyuki Haraguchi and Kazuya Otsubo and Osami Sakata and Akihiko Fujiwara and Hiroshi Kitagawa},
  journal={Inorganic chemistry},
  year={2015},
  volume={54 24},
  pages={11593-5}
}
Highly oriented crystalline thin films of metal-organic frameworks (MOFs) have promising practical applications, such as in gas separation, catalysis, and sensing. We report on the successful fabrication of highly oriented crystalline thin films of three-dimensional porous MOFs, Fe(pz)[M(CN)4] (M = Ni, Pd; pz = pyrazine). Synchrotron X-ray diffraction… CONTINUE READING