Relative energies of dioxo mu-oxo molybdenum complexes from various fragmentation strategies.

Abstract

A thiocyanatomolybdenum(VI) dioxo micro-oxo complex dimer bearing 4,4'-di-tBu-2,2'-bipyridine ligands has shown exceptional oxidizing ability. It exists as a meso form (symmetrical) and a d,l pair (unsymmetrical) in the crystal unit cell and also in equilibrium in solution. Which oxygen atom and which configuration are predominantly involved in the process… (More)

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Cite this paper

@article{Pellegatti2003RelativeEO, title={Relative energies of dioxo mu-oxo molybdenum complexes from various fragmentation strategies.}, author={Alain Pellegatti and Henri Arzoumanian and Bruno J Blaive}, journal={Chemistry}, year={2003}, volume={9 22}, pages={5655-63} }