Regulation of the pore size by shifting the coordination sites of ligands in two MOFs: enhancement of CO2 uptake and selective sensing of nitrobenzene.

Abstract

Two metal-organic frameworks (MOFs), namely {[Cd2(sdb)2(4-bpmh)2(H2O)]}n·2n(H2O) (1), {[Cd2(sdb)2(3-bpmh)2]}n·3n(H2O)·n(C6H5NO) (2), [sdb = 4,4'-sulfonyl dibenzoic acid; 4-bpmh = N,N-bis-pyridin-4-ylmethylene-hydrazine, 3-bpmh = N,N-bis-pyridin-3-ylmethylene-hydrazine, C6H5NO = 3-pyridinecarboxaldehyde] have been synthesized by the solvent diffusion… (More)
DOI: 10.1039/c5dt01976a

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