Regulation of π-stacked anthracene arrangement for fluorescence modulation of organic solid from monomer to excited oligomer emission.

@article{Hinoue2012RegulationO,
  title={Regulation of $\pi$-stacked anthracene arrangement for fluorescence modulation of organic solid from monomer to excited oligomer emission.},
  author={Tomoaki Hinoue and Yuta Shigenoi and Misa Sugino and Yuji Mizobe and Ichiro Hisaki and Mikiji Miyata and Norimitsu Tohnai},
  journal={Chemistry},
  year={2012},
  volume={18 15},
  pages={
          4634-43
        }
}
The construction and precise control of the face-to-face π-stacked arrangements of anthracene fluorophores in the crystalline state led to a remarkable red shift in the fluorescence spectrum due to unprecedented excited oligomer formation. The arrangements were regulated by using organic salts including anthracene-1,5-disulfonic acid (1,5-ADS) and a variety of aliphatic amines. Because of the smaller number of hydrogen atoms at the edge positions and the steric effect of the sulfonate groups, 1… Expand
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