Regioselective syntheses of 2,3,4-tribromopyrrole and 2,3,5-tribromopyrrole.
@article{John2004RegioselectiveSO, title={Regioselective syntheses of 2,3,4-tribromopyrrole and 2,3,5-tribromopyrrole.}, author={E. John and P. Pollet and L. Gelbaum and J. Kubanek}, journal={Journal of natural products}, year={2004}, volume={67 11}, pages={ 1929-31 } }
2,3,4-Tribromopyrrole (1) and 2,3,5-tribromopyrrole (2) were each synthesized from pyrrole. Spectral data and antifeedant effects for synthetic 1 and the antipredatory chemical defense compound of the marine hemichordate Saccoglossus kowalevskii were in agreement, confirming the structure of the deterrent natural product as 1. Spectral data for 2 differed from synthetic and natural 1.
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