Reductive bromine atom-transfer reaction.

@article{Sumino2013ReductiveBA,
  title={Reductive bromine atom-transfer reaction.},
  author={Shuhei Sumino and Akira Fusano and Ilhyong Ryu},
  journal={Organic letters},
  year={2013},
  volume={15 11},
  pages={2826-9}
}
Atom-transfer radical (ATR) reactions of alkenes with R-X usually give products having new C-C and C-X bonds at the adjacent carbons. However, when the reaction was carried out under irradiation using a low-pressure Hg lamp, addition/reduction products were obtained in good yield. Hydrogen bromide, formed by H-abstraction of a bromine radical from alkenes… CONTINUE READING