Reduction of nitroarenes to anilines in basic alcoholic media

  title={Reduction of nitroarenes to anilines in basic alcoholic media},
  author={Maurizio Prato and U. Quintily and Gianfranco Scorrano},
  journal={Journal of The Chemical Society-perkin Transactions 1},
Substituted nitrobenzenes are reduced by alkoxide ions in alcohols to the corresponding azoxy and aniline derivatives. The reaction leading to anilines has been investigated in detail. Two different processes have been identified, both initiated by the condensation between the nitrosoarene intermediate (the first product of the reduction reaction) and the product of oxidation of the solvent. The imino derivative thus formed (ArNCH–COR) may either undergo hydrolysis (to aniline) or form, through… 
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