Reduction of Chlorophyllides, Chlorophylls and Chlorophyll Derivatives by Sodium Borohydride.
@article{Holt1959ReductionOC, title={Reduction of Chlorophyllides, Chlorophylls and Chlorophyll Derivatives by Sodium Borohydride.}, author={A. Holt}, journal={Plant physiology}, year={1959}, volume={34 3}, pages={ 310-4 } }
Sodium borohydride is a well known reducing agent. In methanol at room temperature formyl and keto groups are readily reduced to alcohol groups, while ester and carboxyl groups, carbon-carbon and carbon-nitrogen double bonds are only reduced with difficulty (2, 17). Of the groups present in chlorophyll b the C3 formyl and the C9 keto groups should be amenable to reduction, while the C2 vinyl and the C7 and Ci0 ester groups should be unaffected. Similar considerations apply to chlorophyll a and… Expand
48 Citations
Effects of molecular structures on reduction properties of formyl groups in chlorophylls and pheophytins prepared from oxygenic photosynthetic organisms.
- Chemistry, Medicine
- Bioorganic & medicinal chemistry
- 2011
- 5
Chemical modification of photosystem II core complex pigments with sodium borohydride
- Chemistry, Medicine
- Biochemistry (Moscow)
- 2013
- 2
- PDF
DODECYLPYRIDINIUM ALKANOATES STABILIZE DISPERSED CHLOROPHYLL
- Chemistry, Medicine
- Photochemistry and photobiology
- 1992
- 4
Crystal Structure and Catalytic Mechanism of 7-Hydroxymethyl Chlorophyll a Reductase*
- Chemistry, Medicine
- The Journal of Biological Chemistry
- 2016
- 11
- Highly Influenced
- PDF
Conversion of Chlorophyll b to Chlorophyll a via 7-Hydroxymethyl Chlorophyll (*)
- Chemistry, Medicine
- The Journal of Biological Chemistry
- 1996
- 118
- PDF
References
SHOWING 1-10 OF 25 REFERENCES
The phase test intermediate and the allomerization of chlorophyll a.
- Chemistry, Medicine
- Canadian journal of biochemistry and physiology
- 1958
- 45
Infra-Red Absorption Spectra of Chlorophylls and Derivatives.
- Chemistry, Medicine
- Plant physiology
- 1955
- 49
- PDF
Photosynthetic evolution of oxygen by flashes of light.
- Chemistry, Medicine
- Archives of biochemistry and biophysics
- 1955
- 51
SPECTROSCOPY OF PLANT PIGMENTS I. ETHYL CHLOROPHYLLIDES A AND B AND THEIR PHEOPHORBIDES
- Biology
- 1954
- 101
SPECTROSCOPY OF PLANT PIGMENTS. II. METHYL BACTERIOCHLOROPHYLLIDE AND BACTERIOCHLOROPHYLL
- Biology
- 1954
- 35
Reversible photochemical reduction of chlorophyll by ascorbate
- Compt . rend . ( Doklady ) Acad . Sci . USSR .
- 1948
Vberfuhrung von Dehydro - bakterio - phaophorbid a in Chlorophyll a
- Ann . Chem . , Justus Liebigs
- 1940
Vberfuhrung von Dehydrobakteriophaophorbid a in Chlorophyll a
- Ann . Chem . , Justus Liebigs
- 1940