Recognition of phosphate monoester dianion by an alkoxide-bridged dinuclear zinc(II) complex.

@article{Kinoshita2004RecognitionOP,
  title={Recognition of phosphate monoester dianion by an alkoxide-bridged dinuclear zinc(II) complex.},
  author={Eiji Kinoshita and Makoto Takahashi and Hironori Takeda and Motoo Shiro and Tohru Koike},
  journal={Dalton transactions},
  year={2004},
  volume={8},
  pages={
          1189-93
        }
}
Recognition of phosphate monoester dianion by an alkoxide-bridged dinuclear zinc(II) complex (Zn2L3+) has been studied (L = alkoxide species of 1,3-bis[bis(pyridin-2-ylmethyl)amino]propan-2-ol). Potentiometric pH titration study disclosed a 1 : 1 phenyl phosphate complexation with Zn2L3+ in aqueous solution. The dissociation constant (= [Zn2L3+][PhOPO3(2-)]/[Zn2L3+-PhOPO3(2-)]) is an extremely small value of 2.5 x 10(-8) mol dm(-3) at 25 degrees C with I = 0.10 (NaNO3). The X-ray crystal… CONTINUE READING
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