Readily available pyridine- and quinoline-N-oxides as new organocatalysts for the enantioselective allylation of aromatic aldehydes with allyl(trichloro)silane.

Abstract

The straightforward synthesis of a series of enantiomerically pure pyridine- and quinoline-N-oxides and their use as new organocatalysts for the enantioselective allylation of aromatic aldehydes with allyl(trichloro)silane is reported. The catalysts were readily assembled by combining commercially available enantiopure diamines with heterocyclic carboxylic… (More)

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