Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide.

@article{Hartmann2016ReactivityOA,
  title={Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide.},
  author={Nathaniel J. Hartmann and Guang Wu and Trevor W Hayton},
  journal={Journal of the American Chemical Society},
  year={2016},
  volume={138 38},
  pages={
          12352-5
        }
}
  • Nathaniel J. Hartmann, Guang Wu, Trevor W Hayton
  • Published 2016
  • Medicine, Chemistry
  • Journal of the American Chemical Society
    • The reactivity of the "masked" terminal nickel sulfide complex, [K(18-crown-6)][(L(tBu))Ni(II)(S)] (L(tBu) = {(2,6-(i)Pr2C6H3)NC((t)Bu)}2CH), with the biologically important small molecules CO and NO, was surveyed. [K(18-crown-6)][(L(tBu))Ni(II)(S)] reacts with carbon monoxide (CO) via addition across the Ni-S bond to give a carbonyl sulfide complex, [K(18-crown-6)][(L(tBu))Ni(II)(S,C:η(2)-COS)] (1). Additionally, [K(18-crown-6)][(L(tBu))Ni(II)(S)] reacts with nitric oxide (NO) to yield a… CONTINUE READING
    View on PubMed
    escholarship.org
    12 Citations
    Background Citations
    1

    Topics from this paper

    Explore Further: Topics Discussed in This Paper

    12 Citations
    Citation Type

    Citation Type

    Synthesis of a "Masked" Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids.
    • 1
    Trapping of an NiII Sulfide by a CoI Fulvene Complex
    • 3
    Heteroleptic nickel complexes of a bulky bis(carbene)borate ligand
    • 2
    The hypothiocyanite radical OSCN and its isomers.
    • 4
    Spectroscopic identification of the •SSNO isomers.
    S-Transnitrosation reactions of hydrogen sulfide (H2S/HS-/S2-) with S-nitrosated cysteinyl thiols in phosphate buffer of pH 7.4: Results and review of the literature.
    • 9
    Fundamental chemistry of binary S,N and ternary S,N,O anions: analogues of sulfur oxides and N,O anions.
    • 14
    • PDF
    3D flower-like CoNi2S4/polyaniline with high performance for glycerol electrooxidation in an alkaline medium
    • 6
    3D flower-like Ni–Co–S with high specific surface area for the electrocatalytic oxidation of methanol
    • 14
    Advances in spectroscopy and dynamics of small and medium sized molecules and clusters.
    • M. Hochlaf
    • Chemistry, Medicine
    • Physical chemistry chemical physics : PCCP
    • 2017
    • 25

    References

    SHOWING 1-10 OF 37 REFERENCES
    Activation of CS2 by a "masked" terminal nickel sulfide.
    • 10
    • PDF
    Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide.
    • 11
    • PDF
    Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group.
    • 43
    Nitric oxide reactivity of [2Fe-2S] clusters leading to H2S generation.
    • 20
    Metal-catalyzed "on-demand" production of carbonyl sulfide from carbon monoxide and elemental sulfur.
    • 13
    Atom addition and insertion reactions of (MeCp)2Ta(H)CO with sulfur, tellurium, carbonyl sulfide and carbon disulfide
    • 8
    Reactions of CO(2) and CS(2) with 1,2-bis(di-tert-butylphosphino)ethane complexes of nickel(0) and nickel(I).
    • 70
    Three-Coordinate β-Diketiminato Nickel Nitrosyl Complexes from Nickel(I)−Lutidine and Nickel(II)−Alkyl Precursors
    • 44
    Synthesis and reactivity of NHC-supported Ni2(μ(2)-η(2),η(2)-S2)-bridging disulfide and Ni2(μ-S)2-bridging sulfide complexes.
    • 9
    Synthesis and Structure of a CuI3S Cluster Unsupported by Other Bridging Ligands
    • 10