Reactivity of Au 25 clusters with Au 3

@inproceedings{Muhammed2007ReactivityOA,
  title={Reactivity of Au 25 clusters with Au 3},
  author={Madathumpady Abubaker Habeeb Muhammed and Thalappil Pradeep},
  year={2007}
}
We report the instantaneous decomposition of the small molecular gold cluster, Au25SG18 (SG-glutathione thiolate) in the presence of externally added chloroaurate ions resulting in the instantaneous formation of the insoluble gold–glutathione polymer. The rate of decomposition, however, was much slower for the metal ions such as Ag, Fe, Cu, Ni, Cd, Zn and Sr. This chemical reactivity is shown to have no direct correlation with the electrochemical potential of the added ions. 2007 Elsevier B.V… CONTINUE READING

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