Reactive intermediates in organogermanium chemistry

@article{Satg1984ReactiveII,
  title={Reactive intermediates in organogermanium chemistry},
  author={J. Satg{\'e}},
  journal={Pure and Applied Chemistry},
  year={1984},
  volume={56},
  pages={137 - 150}
}
  • J. Satgé
  • Published 1984
  • Chemistry
  • Pure and Applied Chemistry
New aspects of germylene reactivity are reported. The insertion reactions of halogermylenes into metal—metal bonds of various organometallic compounds lead to trimetallated compounds. The insertion reaction into silicon—transition metal bonds usually leads to unstable adducts which decompose by an n—elimination process to give the first germylenes with germanium—transition metal bonds, These new divalent germanium species give specific germylene reactions. Cycloaddition with 2,3… Expand
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References

SHOWING 1-2 OF 2 REFERENCES
Organosilanes in Comprehensive Organometallic Chern
  • 1982